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Exhibit 13.1

906 CERTIFICATION

The certification set forth below is being submitted in connection with the Annual Report on Form 20-F for the year ended December 31, 2021, for the purpose of complying with Rule 13a-14(b) or Rule 15d-14(b) of the Securities Exchange Act of 1934 (the “Exchange Act”) and Section 1350 of Chapter 63 of Title 18 of the United States Code.

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Fabrizio Barderi, the Chief Executive Officer, and Giuseppe Turchiarelli, the Chief Financial Officer, of Enel Chile S.A., each certifies that, to the best of their knowledge:

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1.the report fully complies with the requirements of Section 13(a) or 15(d) of the Exchange Act; and

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2.the information contained in the report fairly presents, in all material respects, the financial condition and results of operations of Enel Chile.

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Date: April 27, 2022

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/s/ Fabrizio Barderi

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Name: Fabrizio Barderi

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Chief Executive Officer

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/s/ Giuseppe Turchiarelli

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Name: Giuseppe Turchiarelli

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Chief Financial Officer

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